Than the TePP and pentaphenylpyrrole (PPP), both TPM and TPM-Cl displayed prolonged emission wavelengths. Because of their similar toxins formations, this is simply not plausible to characteristic the significant Stokes shift to help you differences in the energy gap between the lower singlet delighted condition (S1) and you can crushed state (S0). I hence suggest that the brand new purple emission represents a minimal triplet thrilled condition (T1), which is below S1. 2, where the curves are the same on their steady-county emission spectra, revealing the fresh long existence services away from both TPM and TPM-Cl. The brand new lifetimes of your own TPM and you may TPM-Cl crystalline powders is actually 20.1 and you can 8.9 μs, respectively (Fig. S3 and you may Table S1).

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Chongqing Wulong Karst Region, Wulong Karst Landscape

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